If you have upgraded Asterisk to 1.4 version you might have problems with the DTMF. To fix this issue you should add to sip.conf the parameter 'rfc2833compensate=yes' to fix the DTMF issue.
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KB » Troubleshooting» DTMF
KB » Troubleshooting» DTMF

I Changed my default DTMF Mode to RFC2833 but I Still Having Problems with the DTMF (Using Asterisk)